The xml file export of the database exports what's in the library (play stats, when the file was added, playlists, "save to database" tags, etc). It does not contain data that's in your files because that data is already accessible to MB within the file itself.
It seems you want to use MB for some purpose other than what's intended (managing a library of media files that the program has access to). MusicBee doesn't store most info that's already in the file in the database as that would be redundant. You're going to have problems doing what you want to do with this program because it's not meant to do it. You're probably better off exporting tags from each set of files (somehow) and managing the list in a spreadsheet or database program.