After reading about how to get 2 way synchronization to finally work (by making sure the Playlist path was not in the Music path), I completely re-synched my micro-SD card, and now music is synching the entire folder path to my card.
For example, My SD card is F:/. Previously all my music would be F:/Artist1, F:/Artist2 etc. Now, my SD Card looks like this:
F:/Music/Users/Joe/Desktop/Joe Music/Artist1
Is there a way to to have the previous layout still preserved?