After a frustrating amount of trial and error, the sequence to make this passable is really quite simple. The trick is to ignore the wording. The option says "automatically synchronise [sic] when the device is connected"... to me, "when" meant "after". But that fails, of course, because it doesn't give you time to click the USB pop-up on the device (and Android 6+ gives no way of defaulting the selection). Instead, you have to have the device already connected and already OK'd the pop-up, THEN launch MusicBee on the computer. Then it works fine.